ORGANIC CHEMISTRY 3371 for Chemistry Majors

Spring 2005, 9:00-9:50 am, EKLC E1B50

Professor Tad Koch

Office: 159 Cristol Chemistry and Biochemistry

Office Hours: T 1:30-2:30, Th 2:30-3:30 or by appointment

Phone: 303-492-6193; e-mail: tad.koch@colorado.edu

Text:     Introduction to Organic Chemistry by Streitwieser, Heathcock and Kosower,

4th Edition, Revised Printing 1998, Macmillan

Solutions Manual and Study Guide, 4th Edition, Revised Printing by Bartlett and Koch

Models: Organic Chemistry Models (Molecular Design, Inc.)

Chem 3371 Recitation and Chem 3341 or 3381 Laboratory must be taken concurrently

Recitation times and rooms are Tue 8:00-8:50 (HALE235) or Wed 5:00-5:50 (HLMS185)

Laboratory times and rooms are MW 1:00-3:50 or TR 9:00-11:50 (ECKL M1B72)

Prerequisite: Chem 3351 with a grade of C- or better

Schedule of Chapters and Testing (work in-text problems plus those assigned below)

Jan. 10 Chapter 15: Aldehydes and Ketones:  Enols; Focus Problems:  4,6,10    

Jan. 12 Homework Problems:  4,5,6,9,10,11,13                                   

Jan. 14 Chapter 16:  Organic Synthesis; Focus Problems:  3e,3f, 4a,5c

Jan. 17 Martin Luther King, Jr., Holiday                            

Jan. 19 Homework Problems:  1,2,3,4,5,6     

Jan. 21 Quiz #1, Chapter 18:  Carboxylic Acids; Focus Problems:  18.6, 8c, 15

Jan. 24 Homework Problems:  1,2,3,4,6,7,8,11,15,16                 

Jan. 26                      

Jan. 28 Quiz #2, Chapter 19:  Derivatives of Carboxylic Acids (course will not focus on Section 19.11, except subsection D); Focus Problems: 6, 12a, 12d, 20           

Jan. 31 Homework Problems: 1,3,5,6,7,8,9,1012,14                     

Feb. 2                           

Feb. 4 Quiz #3, Chapter 20:  Conjugation; Focus Problems: 2,8,14               

Feb. 7    Homework Problems: 1,2,3,4,5,6,8,10,12,14,17,19

Feb. 9 Review

Feb. 10 Exam #1, p.1, p.2, p.3, p.4; 7-9:00 pm in Chem 142

Feb. 11                                                                       

Feb. 14 Chapter 21: Benzene and the Aromatic Ring; Focus Problems: 7,9,12 

Feb. 16 Homework Problems: 1,3,4,5,7,8,9,12,14,18                                                                 

Feb. 18

Feb. 21 Chapter 22: Molecular Orbital Theory; Focus Problems: 3,4,7                                               

Feb. 23 Homework Problems: 1,2,3,4,6,7,8,9,12,15; electrocyclic reaction; general selection rule         

Feb. 25 Quiz #4                                          

Feb. 28 Chapter 23: Electrophilic Aromatic Substitution; Focus Problems: 23.7,4,16

Mar. 2   Homework Problems: 1,4,5,6,7,8,9,11,16,17                   

Mar. 4   Quiz #5                                                                                                                                          

Mar. 7 Chapter 24: Amines; Focus Problems: 17,20,32

Mar. 9  Review

Mar. 10 Exam #2, p.1, p.2, p.3, p.4; 7-9:00 pm in Chem 142

Mar. 11 Homework Problems: 1,2,3,4,5,7,8,9,17,20,23,32

Mar. 14                                              

Mar. 16 Chapter 25:  Other Nitrogen Functions; Focus Problems: 3,13

Mar. 18 Homework Problems: 1,2,3,7,8,9,12,13

Mar. 21 through Mar. 25 Spring Break

Mar. 28

Mar. 30 Chapter 27: Difunctional Compounds; Focus Problems: 7,13

Apr. 1 Quiz #6; Homework Problems: 1,2,4,7,9,10,11,12,13

Apr. 4   

Apr. 6

Apr. 8 Quiz #7; Chapter 28: Carbohydrates; Focus Problems: 6,9,12

Apr. 11 Homework Problems: 4,5,6,7,9,11,12,14,15,16,17,20,26,27                 

Apr. 13 Review

Apr. 14 Exam #3, p.1, p.2, p.3, p.4, p.5; 7-9:00 pm in Chem 142

Apr. 15

Apr. 18 Chapter 29:  Amino Acids and Peptides; Focus Problems: 5,11

Apr. 20 Homework Problems: 1,2,4,5,8,10,11               

Apr. 22 Quiz #8

Apr. 25 Chapter 33:  Mass Spectrometry; Focus Problems:

Apr. 27 Homework Problems:

Apr. 29 Review

May 5   Final Exam, p.1, p.2, p.3, p.4, p.5, p.6, p.7; 7:30-10:00 am in Chem 142 Answers p.1, p.2, p.3, p.4, p.5, p.6, p.7

 

Grading will be based upon performance in three mid-term exams, six quizzes (out of 8) and the final exam. The Mid-term Exams will count 100 points each, the Quizzes 20 points each and the Final Exam will count 200 points. Total points equals 620. All exams and quizzes are mandatory.  Please make arrangements with the instructor ahead of time if a valid reason (e.g. personal illness or injury or death in the immediate family) for missing an exam.  There are no makeup quizzes.  Final grades will be assigned based upon class standing with grades distributed according to a bell shaped curve perturbed slightly toward the higher grades.

Recitations: attendance at one recitation per week is required. Course material, homework problems, quizzes and exams will be discussed during these sessions.

Review sessions are scheduled for the Wednesday lecture hours preceding the Thursday evening Mid-Term exams and the last day of class preceding the Final Exam.

Homework Problems:

The first priority should be to work all the in-text problems as you read each chapter. Work the problems and then consult the Study Guide. Your success will be a measure of your understanding of the immediate material and in some cases your understanding of how it relates to previous material. Selected end-of-text problems will be recommended on a chapter by chapter basis. Some problems similar and/or identical to those in Streitwieser, Heathcock and Kosower will appear on the Quizzes, Mid-term Exams and the Final Exam. The only reasonable way to succeed in organic chemistry is to study and work problems on a regular basis. The "cram and slide" method doesn't work. Regular study will be monitored and rewarded by performance on quizzes. Remember that although the Quizzes count only 20 points each, their sum will contribute 19% toward the final grade!

Web pages:

This version of the syllabus can also be viewed on the undergraduate organic chemistry web page at http://orgchem.colorado.edu (note there is no "www").

If you haven't made flashcards or if you don't like yours, try these from Ohio State University; however, home made is usually better.

An interesting web tutorial on organic nomenclature and stereochemistry is http://people.ouc.bc.ca/woodcock/nomenclature/

A tutorial on IR spectroscopy is available at the undergraduate organic chemistry web page listed above. The specific url is http://orgchem.colorado.edu/hndbksupport/irtutor/tutorial.html.

The software IR Tutor is available through the undergraduate organic lab.

An interesting web site to learn more about NMR spectroscopy is http://www.cis.rit.edu/htbooks/nmr/inside.htm.

Check out the American Chemical Society tabloid newspaper, Chemistry, for students and others interested in chemistry. You don't have to register to read new and old issues of the newspaper.

University Policies:

If you qualify for accommodations because of a disability, please submit a letter to Dr. Koch from Disability Services in a timely manner so that your needs may be addressed. Disability Services determines accommodations based on documented disabilities.  Contact: 303-492-8671, Willard 322, or www.Colorado.EDU/disabilityservices.

Reasonable and appropriate accommodations for students who have conflicts between religious observance dates and course examinations or assignments will be made. Please discuss conflicts with Dr. Koch during the first two weeks of class. The campus policy can be viewed at http://www.colorado.edu/policies/fac_relig.html.

Students and faculty each have responsibility for maintaining an appropriate learning environment. Students who fail to adhere to behavioral standards may be subject to discipline. Faculty have the professional responsibility to treat students with understanding, dignity and respect, to guide classroom discussion and to set reasonable limits on the manner in which students express opinions. See policies at http://www.colorado.edu/policies/classbehavior.html  and at http://www.colorado.edu/studentaffairs/judicialaffairs/code.html#student_code

All students of the University of Colorado at Boulder are responsible for knowing and adhering to the academic integrity policy of this institution. Violations of this policy may include: cheating, plagiarism, aid of academic dishonesty, fabrication, lying, bribery, and threatening behavior.  All incidents of academic misconduct shall be reported to the Honor Code Council (honor@colorado.edu; 303-725-2273). Students who are found to be in violation of the academic integrity policy will be subject to both academic sanctions from the faculty member and non-academic sanctions (including but not limited to university probation, suspension, or expulsion). Additional information on the Honor Code can be found at http://www.colorado.edu/policies/honor.html  and at http://www.colorado.edu/academics/honorcode/

The University of Colorado Policy on Sexual Harassment applies to all students, staff and faculty.  Sexual harassment is unwelcome sexual attention.  It can involve intimidation, threats, coercion, or promises or create an environment that is hostile or offensive. Harassment may occur between members of the same or opposite gender and between any combination of members in the campus community: students, faculty, staff, and administrators. Harassment can occur anywhere on campus, including the classroom, the workplace, or a residence hall.  Any student, staff or faculty member who believes s/he has been sexually harassed should contact the Office of Sexual Harassment (OSH) at 303-492-2127 or the Office of Judicial Affairs at 303-492-5550.  Information about the OSH and the campus resources available to assist individuals who believe they have been sexually harassed can be obtained at: http://www.colorado.edu/sexualharassment/